|本期目录/Table of Contents|

[1]王嘉欣,郝应超,蒋 学,等.β-环糊精接枝改性聚酯纤维织物的亲水性能[J].丝绸,2017,54(8):081103.[doi:10.3969/j.issn.1001-7003.2017.08.003]
 WANG Jiaxin,HAO Yingchao,JIANG Xue,et al.Hydrophilic property of polyester fiber fabrics subject to graft modification by -cyclodextrin[J].Journal of Silk,2017,54(8):081103.[doi:10.3969/j.issn.1001-7003.2017.08.003]
点击复制

β-环糊精接枝改性聚酯纤维织物的亲水性能(PDF)
分享到:

《丝绸》[ISSN:1001-7003/CN:33-1122/TS]

卷:
54
期数:
2017年8期
页码:
081103
栏目:
研究与技术
出版日期:
2017-08-20

文章信息/Info

Title:
Hydrophilic property of polyester fiber fabrics subject to graft modification by -cyclodextrin
文章编号:
1001-7003(2017)08-0013-07
作者:
王嘉欣郝应超蒋 学王鸿博高卫东
1.江南大学 a.纺织服装学院;b.生态纺织教育部重点实验室,江苏 无锡 214122;2.江苏盛虹科技股份有限公司,江苏 苏州 215228
Author(s):
WANG Jiaxin HAO Yingchao JIANG Xue WANG Hongbo GAO Weidong
 1a.College of Textiles and Clothing;1b.Key Laboratory of Eco-textiles, Ministry of Education, Jiangnan University, Wuxi 214122, China; 2.Sheng Hong Group Holdings Limited, Suzhou 215228, China
关键词:
聚酯纤维织物β-环糊精1234-丁烷四羧酸亲水性能轧烘焙
Keywords:
Polyester fiber fabric -cyclodextrin 1234-butane tetra carboxylic acid hydrophilicity pad-dry-cure
分类号:
TS195.6
doi:
10.3969/j.issn.1001-7003.2017.08.003
文献标志码:
A
摘要:
采用轧烘焙工艺引发β-环糊精对聚酯纤维织物进行接枝,探讨以1,2,3,4-丁烷四羧酸为交联剂、次亚磷酸钠为催化剂的条件下接枝环糊精以期提高聚酯纤维织物亲水性能的工艺条件。研究得出:β-环糊精处理聚酯纤维织物的最佳条件是β-环糊精质量浓度100 g/L,与丁烷四羧酸的摩尔比1︰3;烘焙的最佳条件是低温烘干6 min,高温烘焙3 min。回潮率测试结果表明,改性聚酯纤维织物的回潮率随接枝率的增加而逐渐增大,当接枝率达到最大值16.11%时,改性聚酯纤维织物的回潮率可达2.18%。聚酯纤维织物经30次洗涤后减重率控制在2%以内,说明接枝牢度优异。
Abstract:
Graft modification of polyester fiber fabric with β-cyclodextrin was initiated with pad-dry-cure process, to discuss the technological conditions for improving the hydrophilic property of polyester fiber fabric with 1,2,3,4-butane tetra carboxylic acid as cross linking agent and s odium hypophosphite as catalyst. Research shows that the optimum condition s for processing polyester fiber fabric with β-cyclodextrin are: mass concentration of β-cyclodextrin: 100 g/L, and molar ratio of β-cyclodextrin to butane tetra carboxylic acid: 1:3; the optimum cure conditions are: drying at low temperature for 6 minutes , and drying at high temperature for 3 minutes. T he test result of moisture regain suggests that the moisture regain of modified polymer fiber fabric gradually rises with the increase of grafting ratio, and can reach up to 2.18% as the grafting ratio reaches the maximum (16.11%). The weight-loss ratio of polymer fiber fabric remains within 2% after washing 30 times, indicating that it is of good grafting fastness.

参考文献/References:

[1]陈丽, 王潮霞. 涤纶喷墨印花织物的柠檬酸-β-环糊精预处理[J]. 纺织学报, 2011, 32(3):100-104.
CHEN Li, WANG Chaoxia. Synthesis and application of CTR-β-CD for inkjet printer fabric pretreatment[J]. Journal of Textile Research, 2011, 32(3): 100-104.
[2]李卫红, 荆妙蕾, 关静, 等. 环糊精接枝纺织纤维的研究进展[J]. 天津工业大学学报, 2011, 30(6): 48-52.
LI Weihong, JING Miaolei, GUAN Jing, et al. Research progress of textile fibers grafted by cyclodextrin[J].Journal of Tianjin Polytechnic University, 2011, 30(6): 48-52.
[3]陈丽. 环糊精的改性及在纺织中的应用研究[D]. 无锡: 江南大学, 2012.
CHEN Li. Investigation on Cyclodextrin Modification and Application Properties in Textiles[D].Wuxi: Jiangnan University, 2012.
[4]贺昌城, 顾振亚. 丙烯酸接枝涤纶织物性能的研究[J]. 合成纤维, 2005, 34(5): 29-32.
HE Changcheng, GU Zhenya. Investigation on properties of a crylic-acid G rafted PET fabric[J]. Synthetic Fiber in China, 2005, 34(5): 29-32.
[5]王春梅. 环糊精在染整加工中的应用[J]. 丝绸, 2005(12): 35-37.
WANG Chunmei.Applications of cyclodextrins in textile dyeing and finishing[J]. Journal of Silk, 2005(12): 35-37.
[6]王蕾, 殷亚辉. 环糊精整理织物的技术开发[J]. 印染, 2004, 30(8): 47-49.
WANG Lei, YIN Yahui. Cyclodextrin finishing of fabric[J]. Dyeing & Finishing, 2004, 30(8): 47-49.
[7]陈丽, 王潮霞. 环糊精在纺织品加工中的应用[J]. 印染助剂, 2009, 26(3): 6-9.
CHEN Li, WANG Chaoxia. Application of cyclodextrins in textile processing[J]. Textile Auxiliaries, 2009, 26(3): 6-9.
[8]刘夺奎, 顾振亚, 董振礼. 环糊精在纺织染整加工中应用的新进展[J]. 染整技术, 2003, 25(3): 12-15.
LIU Duokui, GU Zhenya, DONG Zhenli. Application of cyclodextrin in textile dyeing and finishing[J]. Textile Dyeing and Finishing Journal, 2003, 25(3): 12-15.
[9]李淑华, 顾晓梅, 周林芳. 环糊精及其衍生物在织物功能整理方面的应用[J]. 纺织导报, 2007(2): 68-72.
LI Shuhua, GU Xiaomei, ZHOU Linfang. Application of cyclodextrins and its derivates in the functional finishing of textiles[J]. China Textile Leader, 2007(2): 68-72.
[10]KNITTEL D, THOMS G, J.BUSCHMANN H, 等. 非传统的纺织品后整理(第一部分): 以一氯三嗪-β-环糊精为粘合剂的多种功能整理[J]. 国际纺织导报, 2007, 35(3): 54-58.
KNITTEL D, THOMS G, J.BUSCHMANN H, et al. Unconventional textile finishes (part 1): monochlorotriazinyl -β- cyclodextrin as anchoring chemical for various functional finishes[J]. Melliand China, 2007, 35(3): 54-58.
[11]魏赛男, 党宁, 吴焕领, 等. 涤纶亲水性后整理的现状[J]. 合成纤维工业, 2007, 30(6): 47-49.
WEI Sainan, DANG Ning, WU Huanling, et al. Current situation of hydrophilic finish treatment for PET fiber[J]. China Synthetic Fiber Industry, 2007, 30(6): 47-49.
[12]王春梅. β-环糊精在织物整理中的应用研究[D]. 上海: 东华大学, 2011.
WANG Chunmei. Applicstions of β- cyelodextrinintcxtile Finishing[D]. Shanghai: Donghua University, 2011.
[13]陈鑫涛, 王罗新, 蔡静平, 等. 环糊精在聚合反应中的应用研究进展[J]. 天津工业大学学报, 2010, 29(6): 54-62.
CHEN Xintao, WANG Luoxin, CAI Jingping, et al. Progress of applications of cyclodextrin in polymerization[J]. Journal of Tianjin Polytechnic University, 2010, 29(6): 54-62.
[14]邱红娟, 许敏, 龚蕴玉, 等. 环糊精的性质及在染整加工上的应用[J]. 四川丝绸, 2001(4): 26-30.
QIU Hongjuan, XU Min, GONG Yunyu, et al. The properties of cyclodextrin and its application in dyeing and finishing process[J]. Sichuan Silk, 2001(4): 26-30.
[15]代国亮, 肖红, 施楣梧. 涤纶表面亲水改性研究进展及其发展方向[J]. 纺织学报,2015, 36(8): 156-164.
DAI Guoliang, XIAO Hong, SHI Meiwu. Research progress and development direction of surface hydrophilic modification of polyester fiber[J]. Journal of Textile Research, 2015, 36(8): 156-164.
[16]石小丽. 涤纶纤维制品自由基接枝聚合改性及其应用性能研究[D]. 苏州: 苏州大学, 2007.
SHI Xiaoli. Study on Modification of Poly (Ethylene Terephthalate ) by Free Radical Grafting Polymerization and Its Performance[D]. Suzhou: Soochow University, 2007.
[17]李光, 顾利霞. 亲水性涤纶的最新发展[J]. 合成技术及应用, 1995(3): 33-36.
LI Guang, GU Lixia. The new developments of hydrophilic polyester fiber[J]. Synthesis Technology and Application, 1995(3): 33-36.
[18]陈秋圆, 刘开强, 唐人成. 涤纶织物聚酯聚醚共聚物浸渍法亲水整理[J]. 印染, 2013(1): 1-4.
CHEN Qiuyuan, LIU Kaiqiang, TANG Rencheng. Hydrophilic finish of polyester fiber with polyester-polyether block copolymer by an immersion method[J]. Dyeing & Finishing, 2013(1): 1-4.
[19]魏赛男, 刘超颖, 张长伟. 后整理技术在聚酯织物上的应用[J]. 河北工业科技, 2008, 25(5): 335-338.
WEI Sainan, LIU Chaoying, ZHANG Changwei. Application of finishing technology on polyester fabric[J]. Hebei Journal of Industrial Science and Technology, 2008, 25(5): 335-338.
[20]LI Chen, WANG Chaoxia, TIAN Anli, et al. An attempt of improving polyester inkjet printing performance by surface modification using β-cyclodextrin[J]. Surface Interface Anal, 2012, 44(10): 1324-1330.
[21]LOUIS Poon, LEE D Wilson, JOHN V Headley. Preparation and sorption properties of tunable polyester copolymers containing β-cyclodextrin[J]. Journal Application Polymer, 2013, 127(6): 4889-4898.
[22]JONG S Park, KIM Ik-Soo. Use of β-cyclodextrin in an antimigration coating for polyester fabric[J]. Coloration Technology, 2013, 129(5): 347-351.
[23]?OR?EVI? Dragan, NOVAKOVI? Mile, KONSTANTINOVI ? Sandra. The application of cyclodextrins in textile area[J]. Hemijska Industrija, 2006, 60(9/10): 259-268.
[24]ROSARINA Carpignano, STEFANIA Parlati, PAOLA Piccinini, et al. Use of β-cyclodextrin in the dyeing of polyester with low environmental impact[J]. Coloration Technology, 2010, 126(4): 201-208.
[25]MONTAZER M, JOLAEI M M. β-Cyclodextrin stabilized on three-dimensional polyester fabric with different crosslinking agents[J]. Journal of Application Polymer, 2010, 116(1): 210-217.

备注/Memo

备注/Memo:
收稿日期:2016-11-29
修回日期:2017-00-00基金项目:中央高校基本科研业务费资助项目(JUSRP51622A、JUSRP51515);国家自然科学基金项目(31570578);江苏高校优势学科建设工程项目(JHB20苏政办发137号)
作者简介:王嘉欣(1993—),女,硕士研究生,研究方向为功能纺织品
通信作者:蒋学,教授,xue.jiang@163.com
更新日期/Last Update: 2017-06-30